New Long-Lived Greenhouse Gas Discovered

http://www.sciencedaily.com/releases/2013/12/131209124101.htm

Dec. 9, 2013 — Scientists from U of T's Department of Chemistry have discovered a novel chemical lurking in the atmosphere that appears to be a long-lived greenhouse gas (LLGHG). The chemical -- perfluorotributylamine (PFTBA) -- is the most radiatively efficient chemical found to date, breaking all other chemical records for its potential to impact climate.

Radiative efficiency describes how effectively a molecule can affect climate. This value is then multiplied by its atmospheric concentration to determine the total climate impact.

FTBA has been in use since the mid-20th century for various applications in electrical equipment and is currently used in thermally and chemically stable liquids marketed for use in electronic testing and as heat transfer agents. It does not occur naturally, that is, it is produced by humans. There are no known processes that would destroy or remove PFTBA in the lower atmosphere so it has a very long lifetime, possibly hundreds of years, and is destroyed in the upper atmosphere.

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Carbon dioxide (CO2) is used as the baseline for comparison since it is the most important greenhouse gas responsible for human-induced climate change. "PFTBA is extremely long-lived in the atmosphere and it has a very high radiative efficiency; the result of this is a very high global warming potential. Calculated over a 100-year timeframe, a single molecule of PFTBA has the equivalent climate impact as 7100 molecules of CO2," said Hong.